Observation of MEL stacking faults in two-dimensional MFI zeolite nanosheets
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چکیده
منابع مشابه
Crystallographic Structure Determination of MFI-Zeolite Nanosheets
Ultrathin MFI-zeolite nanosheets can be packed on porous supports to create molecular sieve membranes. The nanosheets on porous support reduce morphological damage seen in regular MFIzeolite crystals [1]. MFI-zeolite belongs to pentasil family of zeolites where the periodic building unit (PerBU) is composed of 12 interconnected SiO4 tetrahedral (T12) units of 41m2 (D2d) symmetry [2]. Rotation o...
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Two-dimensional zeolite nanosheets that do not contain any organic structure-directing agents were prepared from a multilamellar MFI (ML-MFI) zeolite. ML-MFI was first exfoliated by melt compounding and then detemplated by treatment with a mixture of H2 SO4 and H2 O2 (piranha solution). The obtained OSDA-free MFI nanosheets disperse well in water and can be used for coating applications. Deposi...
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Stable suspensions of zeolite nanosheets (3 nm thick MFI layers) were prepared in ethanol following acid treatment, which partially removed the associated organic structure-directing agent. Nanosheets from these suspensions could then be dispersed at the air-water interface and transferred to silicon wafers using Langmuir-Schaefer deposition. Using layer-by-layer deposition, control on coating ...
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zeolite thin films Jin Fang, Yi Huang, Christopher M. Lew, Yushan Yan, and Laurent Pilon Department of Mechanical and Aerospace Engineering, Henry Samueli School of Engineering and Applied Science, University of California-Los Angeles 420 Westwood Plaza, Los Angeles, California 90095, USA Department of Chemical Engineering and Materials Science, University of Minnesota Minneapolis, Minnesota 55...
متن کاملMFI zeolite nanosheets with post-synthetic Ti grafting for catalytic epoxidation of bulky olefins using H2O2.
The external surfaces of the surfactant-directed, 2.5 nm MFI zeolite nanosheets were grafted with Ti using titanium(IV) butoxide. The Ti/MFI nanosheets exhibited a remarkable catalytic performance for epoxidation of bulky olefins using H2O2 as an oxidant, in comparison to the mesoporous silicas with amorphous frameworks.
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ژورنال
عنوان ژورنال: Microscopy and Microanalysis
سال: 2016
ISSN: 1431-9276,1435-8115
DOI: 10.1017/s1431927616009016